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Journal Articles

Extreme chemistry of superheavy elements

Sato, Tetsuya; Nagame, Yuichiro*

Nihon Butsuri Gakkai-Shi, 78(2), p.64 - 72, 2023/02

The study of the chemistry of superheavy elements, which are located in the heavy extremes of the periodic table, has made considerable progress over the past 20 years, and new approaches based on various ideas have recently been developed. Research groups in Japan have also made significant contributions to the development of research on superheavy elements. Recently, notable results have been reported for the transactinide elements rutherfordium (element 104), dubnium (element 105), and seaborgium (element 106), and the heavy actinides with atomic numbers exceeding 100. The review will focus on the recent main results of these elements. This review outlines the main recent results and touches on future prospects.

Journal Articles

Production and chemistry of transactinide elements

Nagame, Yuichiro

Journal of Nuclear and Radiochemical Sciences, 6(3), p.205 - 210, 2005/12

no abstracts in English

Journal Articles

Radiochemical studies of the transactinide element, rutherfordium (Rf) at JAERI

Nagame, Yuichiro

Journal of Nuclear and Radiochemical Sciences, 6(2), p.A21 - A28, 2005/12

no abstracts in English

Journal Articles

Transactinide element research; Present status and perspectives

Nagame, Yuichiro

Radioisotopes, 54(11), p.555 - 567, 2005/11

no abstracts in English

Journal Articles

Chemical studies of the heaviest elements

Nagame, Yuichiro; Haba, Hiromitsu*; Tsukada, Kazuaki; Asai, Masato; Toyoshima, Atsushi; Goto, Shinichi*; Akiyama, Kazuhiko; Kaneko, Tetsuya; Sakama, Minoru*; Hirata, Masaru; et al.

Nuclear Physics A, 734, p.124 - 135, 2004/04

 Times Cited Count:11 Percentile:56.87(Physics, Nuclear)

no abstracts in English

JAEA Reports

Proceedings of the 2nd Workshop on the Nuclear Sciences of the Heaviest Elements; February, 22-23, 2001, JAERI, Tokai, Japan

Tsukada, Kazuaki; Nagame, Yuichiro

JAERI-Conf 2003-007, 108 Pages, 2003/06

JAERI-Conf-2003-007.pdf:7.81MB

no abstracts in English

Journal Articles

Isothermal gas chromatography of chlorides of Zr and Hf as Rf homologs

Kaneko, Tetsuya*; Ono, Sawako*; Goto, Shinichi*; Haba, Hiromitsu; Asai, Masato; Tsukada, Kazuaki; Nagame, Yuichiro; Kudo, Hisaaki*

Journal of Radioanalytical and Nuclear Chemistry, 255(2), p.381 - 384, 2003/02

 Times Cited Count:0 Percentile:0.01(Chemistry, Analytical)

no abstracts in English

Journal Articles

Transactinide nuclear chemistry at JAERI

Nagame, Yuichiro; Haba, Hiromitsu; Tsukada, Kazuaki; Asai, Masato; Akiyama, Kazuhiko; Hirata, Masaru; Nishinaka, Ichiro; Ichikawa, Shinichi; Nakahara, Hiromichi; Goto, Shinichi*; et al.

Czechoslovak Journal of Physics, 53, p.A299 - A304, 2003/00

 Times Cited Count:7 Percentile:46.48(Physics, Multidisciplinary)

no abstracts in English

Journal Articles

Status and prospects of Heavy element nuclear chemistry research at JAERI

Nagame, Yuichiro; Asai, Masato; Haba, Hiromitsu; Tsukada, Kazuaki; Goto, Shinichi; Sakama, Minoru; Nishinaka, Ichiro; Toyoshima, Atsushi; Akiyama, Kazuhiko; Ichikawa, Shinichi

Journal of Nuclear and Radiochemical Sciences, 3(1), p.129 - 132, 2002/06

no abstracts in English

Journal Articles

Startup of transactinide chemistry in JAERI

Haba, Hiromitsu; Tsukada, Kazuaki; Asai, Masato; Nishinaka, Ichiro; Sakama, Minoru*; Goto, Shinichi*; Hirata, Masaru; Ichikawa, Shinichi; Nagame, Yuichiro; Kaneko, Tetsuya*; et al.

Radiochimica Acta, 89(11-12), p.733 - 736, 2002/02

 Times Cited Count:15 Percentile:68.91(Chemistry, Inorganic & Nuclear)

no abstracts in English

Journal Articles

Chemical property of element 107 bohrium

Haba, Hiromitsu

Kagaku To Kogyo, 54(5), P. 590, 2001/00

no abstracts in English

Journal Articles

Frontiers of superheavy elements; Synthesis and chemistry

Nagame, Yuichiro; Kudo, Hisaaki*; Shinohara, Atsushi*

Radioisotopes, 49(7), p.363 - 375, 2000/07

no abstracts in English

JAEA Reports

Proceedings of the Workshop on the Nuclear Sciences of the heaviest elements; July 21-22, 1999, JAERI, Tokai, Japan

Nagame, Yuichiro; Haba, Hiromitsu; Ikezoe, Hiroshi

JAERI-Conf 2000-002, p.103 - 0, 2000/03

JAERI-Conf-2000-002.pdf:4.77MB

no abstracts in English

Journal Articles

Chromatographic studies of rutherfordium (element 104) with tributylphosphate

Br$"u$chle, W.*; Eichler, B.*; G$"a$ggeler, H. W.*; Guenther, R.*; J$"a$ger, E.*; Jost, D.*; Kratz, J. V.*; Nagame, Yuichiro; Paulus, W.*; Pershina, V.*; et al.

Proceedings of 1st International Conference on the Chemistry and Physics of the Transactinide Elements, 3 Pages, 1999/00

no abstracts in English

Journal Articles

Chemical properties of element 106

Tsukada, Kazuaki

Kagaku To Kogyo, 51(4), P. 615, 1998/00

no abstracts in English

Journal Articles

Heavy elements; Synthesis and chemical properties

Nagame, Yuichiro

Kagaku To Kyoiku, 44(11), p.712 - 713, 1996/00

no abstracts in English

Journal Articles

Chemistry of transactinide elements

Shinohara, Nobuo; Usuda, Shigekazu

Nihon Genshiryoku Gakkai-Shi, 37(10), p.907 - 913, 1995/00

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

no abstracts in English

Oral presentation

Developments towards aqueous phase chemistry of transactinide elements

Toyoshima, Atsushi; Oe, Kazuhiro*; Asai, Masato; Attallah, M. F.*; Goto, Naoya*; Gupta, N. S.*; Haba, Hiromitsu*; Kaneko, Masashi*; Kaneya, Yusuke; Kasamatsu, Yoshitaka*; et al.

no journal, , 

Due to short half-lives less than 10 s and extremely low production rates, transactinide elements heavier than seaborgium (Sg) are produced on an atom per hour scale. Therefore, a continuous rapid chemistry assembly is required to study aqueous-phase chemistry of these heaviest elements. In the present study, we started developments of a continuous chemistry assembly. Our first attempt was made in on-line experiments with Mo and W, lighter homologs of Sg, to optimize a chemistry assembly consisting of a newly developed membrane degasser as an interface between gas-jet and aqueous phase, a flow electrolytic column apparatus utilized to control oxidation states of Mo and W ions, and the continuous liquid-liquid extraction apparatus of SISAK for separation. In the conference, present status of the developments will be presented.

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